We have tested different combinations of fabrics together for both layering purposes but also when used together as a clothing system. They air gap which is create between layers offers a substantial increase in the amount of energy it blocks. While we do not have complete data on our website you can view the chart at the bottom of this page; its a system for a lined jacket.
http://benchmarkfr.com/flame-resistant-clothing/outerwear/ at the bottom you will see a graph which graphically represents the increase in thermal protection.
This graphical representation shows two twill fabrics (6.3 & 13.2 cal) which if simply added together would equal 19.5 cal, however when tested together they achieved a 32 cal rating.
The only way to determine the arc thermal protective value from multiple layers is to actually test the layers together. It is important to note there is an anomaly called ablation or "double hump" which must be considered when testing fabrics which are not the same weight. If we reversed the layers and tested the lighter layer toward the outside it would have created a different ATPV for the system.